Non-Contact Atomic Force Microscopy

Staff: Roland Coratger, Sébastien Gauthier, André Gourdon, Olivier Guillermet, Véronique Langlais, David Martrou
Ph.D. students & Postdocs: Florian Chaumeton, Antoine Hinaut, Thomas Léoni, Adeline Pujol, Hermann Walch, Loranne Vernisse
Microscopie à force atomique
Molecular resolution NC-AFM image of the top facet of an island of hexamethoxytriphenylene adsorbed on KBr(001)
Experiments are performed with two types of microscopes:
- At room temperature, with silicon cantilevers, with the goal of imaging single molecules adsorged on surfaces of insulators
- At low temperature, with tuning forks (qPlus sensors), with the goal of imaging molecules adsorbed on thin insulating films deposited on metallic surfaces, allowing the simultaneous use of scanning tunnling microscopy.
Microscopie à force atomique
Constant-height image of the frequency shift above a decastarphene molecule adsorbed on Cu(111) at 5 K.
These nc-afm experiments can be coupled with Kelvin Probe Force Microscopy (KPFM) measurements to characterize electrostatic surface properties such as dipolar moment or charge distributions of an adsorbate on a metallic or insulating substrate.
Microscopie à force atomique
(a) Constant frequency shift and (b) Kelvin image of a deposit of hexa(cyanopropyloxy)triphenylene on KBr(001). The Kelvin signal indicates that a dipole pointing toward vacuum is associated with the two types of monolayers that are observed (MLh and MLv).

Selected publications

  • A NC-AFM study of the adsorption of hexamethoxytriphenylene on KBr(001), A. Hinaut, K. Lekhal, G. Aivazian, S. Bataillé, A. Gourdon, D. Martrou and S. Gauthier, J. Phys. Chem. C, 115(27), pp 13338-13342 (2011)
  • STM and AFM high resolution intramolecular imaging of a single decastarphene molecule, Olivier Guillermet, Sébastien Gauthier, Christian Joachim, Paula de Mendoza, Thorsten Lauterbach, Antonio Echavarren. Chem. Phys. Lett., Volume 511, Issues 4-6, pp 482-485 (2011)
  • An NC-AFM and KPFM study of the adsorption of a triphenylene derivative on KBr(001), Antoine Hinaut, Adeline Pujol, Florian Chaumeton, David Martrou, André Gourdon and Sébastien Gauthier, Beilstein J. Nanotechnol. 2012, 3, 221–229.