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Stress and nanostructuration
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| Marie-José Casanove, Nicolas
Combe, François Demangeot, Lise Durand, Christophe Gatel, Joseph
Morillo, Anne Ponchet, André Rocher, Christian Roucau, Hao
Tang |
| This thematic is devoted to the role of the internal
stresses in the growth and properties of thin layers, multilayers
and quantum dots which are involved in optoelectronic, magnetic
or microelectronic devices. In these nanostructures, stresses are
due to the presence of interfaces, of lattice mismatches (epitaxial
stress), or are generated during the process (thermal stresses…).
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Internal stresses result in a modification of the crystalline
symmetry and of the physical properties. They intervene in the growth
mechanisms and are likely to affect the device stability.
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InAs island grown by MBE on (113)B InP. Appl.
Phys. Lett. 74, 1680 (1999). |
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We also study how internal stresses can be exploited for the nanotructuration,
i.e. the spatial organisation of nano-objects, thanks to self-assembly
processes (competition between molecule-molecule interactions and
molecules-surface interaction, Stranski-Krastanov growth mode…)
and to the use of specific surfaces (non conventional orientation,
surface etching…).
We develop experimental studies (transmission electron microscopy,
optical and Raman micro-spectroscopy), modelling at the atomic scale,
and new methods for measuring stress and strain. The nanostructures
studied include semiconductors, metallic oxides, and hybrid organic-inorganic
systems.
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Epitaxial growth of MgO on (001)MgO : modelisation
by DFT (density functional theory) of the nucleation mechanisms
(a) diffusion of Mg, (b) rotation of O, and (c) formation of a MgO
molecule Surface Science 601, 5616 (2007). |
Research topics: |
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Key-words:
epitaxy, self-organisation, elastic relaxation, plastic relaxation,
III-V semiconductor, gallium nitride, GaN, organic-inorganic system,
TEM, Raman, DFT, Kinetic Monte Carlo.
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